Sigma-Aldrich
P-Benzoquinone Reagent Grade 98% 1 kg
- Part Number:
- MIL-B10358-1KG
- Lead Time:
- 7-14 days
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- Quantity:
- each
- Size:
- 1 kg
- Style:
- chemical
- DOT Rated:
- HazMat Transport Fee Required
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Description
P-Benzoquinone Reagent Grade ≥98% 1 Kg
Synonym: Quinone
- CAS Number 106-51-4
- Linear Formula C6H4(=O)2
- Molecular Weight 108.09
- Beilstein/REAXYS Number 773967
- EC Number 203-405-2
- MDL number MFCD00001591
- PubChem Substance ID 57653913
- NACRES NA.21
| grade | reagent grade |
| vapor density | 3.73 (vs air) |
| vapor pressure | 0.1 mmHg ( 25 °C) |
| assay | ≥98% |
| autoignition temp. | 815 °F |
| greener alternative product characteristics | CatalysisLearn more about the Principles of Green Chemistry. |
| mp | 113-115 °C (lit.) |
| SMILES string | O=C1C=CC(=O)C=C1 |
| InChI | 1S/C6H4O2/c7-5-1-2-6(8)4-3-5/h1-4H |
| InChI key | AZQWKYJCGOJGHM-UHFFFAOYSA-N |
| Gene Information | human ... ACHE(43), BCHE(590), CES1(1066) |
General description
p-Benzoquinone (PBQ) is a cyclic conjugated diketone. Its high-resolution photoelectron spectrum has been reported. The visible and near ultraviolet spectra of PBQ have been recorded and analyzed. Its addition as coagent has been reported to enhance the crosslinking rate of polypropylene initiated by the pyrolysis of peroxides. Its impact on hemoglobin (Hb) has been investigated based on immunoblots and mass spectral analysis of a smoker′s blood.
Free radical inhibitor
Application
p-Benzoquinone may be used to form benzofuranone derivatives on reacting with anilides of β-aminocrotonic acids via Nenitzescu reaction.
Dienophile employed in Diels-Alder cycloadditions to form naphthoquinones, and 1,4-phenanthrenediones.
Oxidant used in first step of greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.
GHS06, GHS09
Signal word Danger
Hazard statements H301 + H331-H315-H319-H335-H410
Precautionary statements P261-P273-P301 + P310 + P330-P304 + P340 + P312-P403 + P233-P501
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR UN 2587 6.1 / PGII
WGK Germany 3
RTECS DK2625000
Documents
Warnings
Note: These chemicals are for research & laboratory use only. Your order will not be processed if you do not work for, and ship to, a registered laboratory or research facility. Not for topical applications. An official Declaration of Use form may be required.
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WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning
Please note: This product is not returnable.