Sigma-Aldrich

2-Methyltetrahydrofuran, Reagent Plus® 99.5%+, 2.5 Liter

Part Number:
MIL-155810-25L
Lead Time:
2-4 weeks
Shipping:
FREE SHIPPING on most orders over $50*
Quantity:
each
Size:
2.5 liter
Style:
chemical
DOT Rated:
HazMat Transport Fee Required
Price: $395.58

Bulk discount rates

Automatically save when you buy in bulk.

Buy 6 - 11 and get 10% off
Buy 12 or above and get 15% off

Description

2-Methyltetrahydrofuran ReagentPlus ≥99.5% 200 Liter

Synonym: 2-MeTHF, Tetrahydro-2-methylfuran, Tetrahydrosilvan

  • CAS Number 96-47-9
  • Empirical Formula (Hill Notation) C5H10O
  • Molecular Weight 86.13
  • Beilstein/REAXYS Number 102448
  • EC Number 202-507-4
  • MDL number MFCD00005367
  • PubChem Substance ID 329750937
Grade ReagentPlus®
InChI Key JWUJQDFVADABEY-UHFFFAOYSA-N
Assay ≥99.5%
contains 150-400 ppm BHT as stabilizer
Expl. Lim. 0.34-6.3 %
greener alternative
product characteristics

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.
Impurities

≤1.0% water ((coulometric.))
≤100 ppm peroxide (as H2O2)
Refractive Index n20/D 1.406 (lit.)
bp 78-80°C(lit.)
mp -136°C
Density 0.86 g/mL at 25°C (lit.)

General description

2-Methyltetrahydrofuran is an environmentally favorable alternative to tetrahydrofuran (THF), 1,4 Dioxane (Dioxane) and dichloromethane (DCM) for most industrial applications.

  • Many of its benefits include:
  • High boiling point
  • Clean organic-water phase separation
  • Reduced energy to recover

Application

  • Alternative for THF in Organometallic reactions:
  • Grignard
  • Reformantsky
  • Lithiation
  • Hydride Reduction
  • Metal-Catalyzed Coupling (Heck, Stile, Suzuki)

Alternative to Dichloromethane for Biphasic Reactions:

  • Alkylation
  • Amidation
  • Nucleophilic Substitution

Forms organic (non-crystalline) glass for low temperature (-196°C) spectroscopic studies.

Green Alternatives to DCM and THF from Renewable resources

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Safety Information

GHS02GHS05GHS07 GHS02, GHS05, GHS07

Signal word Danger
Hazard statements H225-H302-H315-H318
Precautionary statements P210-P280-P301 + P312 + P330-P305 + P351 + P338 + P310-P370 + P378-P403 + P235
Supplemental Hazard Statements May form explosive peroxides.
RIDADR UN 2536 3 / PGII
WGK Germany 2RTECS LU2800000
Flash Point(F) 14°F
Flash Point(C) -10°C

Documents

Safety Data Sheet

Warnings

Note: These chemicals are for research & laboratory use only. Your order will not be processed if you do not work for, and ship to, a registered laboratory or research facility. Not for topical applications. An official Declaration of Use form may be required.

Most chemicals cannot be expedited.

This item has a Haz-Mat shipping fee built into the price. Fee is applicable only to the first item purchased. Additional HazMat items will be discounted automatically in the shopping cart. HazMat items always require special DOT handling and in rare cases may incur additional fees not levied prior to checkout. Request a quote for the most accurate pricing.

WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning

Please note: This product is not returnable.

View AllClose

0 Reviews

View AllClose
MPN:
155810-2.5L